Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory

af John Telotte

Abstract: A solution of groups technique was developed for use with fluctuation solution theory. The general expressions for calculation of pressure and chemical potential changes from some fixed reference states have been shown. A new corresponding states theory correlation for direct correlation function integrals was proposed and used with the group contribution technique for calculation of pressure changes during compression for several n-alkanes and methanol. This work gives a detailed anal... (Læs mere)